Acta Crystallographica Section E (Dec 2012)

(3aRS,7aSR)-7a-Methoxy-2-oxo-2,3,3a,4,5,6,7,7a-octahydro-1-benzofuran-4,4-dicarbonitrile

  • María González,
  • Andrea Martínez,
  • Marcos L. Rivadulla,
  • Berta Covelo

DOI
https://doi.org/10.1107/S1600536812048519
Journal volume & issue
Vol. 68, no. 12
pp. o3496 – o3496

Abstract

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The racemic title compound, C11H12N2O3, contains a [4.3.0]bicyclic unit in which the shared C—C bond adopts a cis configuration. The five- and six-membered rings are in twisted envelope (with the bridgehead C atom bearing the methoxy substituent as the flap) and distorted chair conformations, respectively. In the crystal, the molecules are linked via weak C—H...O iteractions, forming ladder-like chains along [010].