Influence of Pd and Pt Promotion in Gold Based Bimetallic Catalysts on Selectivity Modulation in Furfural Base-Free Oxidation

Abstract

Furfural (FF) has a high potential to become a major renewable platform molecule to produce biofuels and bio-based chemicals. The catalytic performances of AuxPty and AuxPdy bimetallic nanoparticulate systems supported on TiO2 were studied in a base-free aerobic oxidation of furfural to furoic acid (FA) and maleic acid (MA) in water. The characterization of the catalysts was performed using standard techniques. The optimum reaction conditions were also investigated, including the reaction time, the reaction temperature, the metal ratio, and the metal loading. The present work shows a synergistic effect existing between Au, Pd, and Pt in the alloy, where the performances of the catalysts were strongly dependent on the metal ratio. The highest selectivity (100%) to FA was obtained using Au3-Pd1 catalysts, with 88% using 0.5% Au3Pt1 with about 30% of FF conversion at 80 °C. Using Au-Pd-based catalysts, the maximum yield of MA (14%) and 5% of 2(5H)-furanone (FAO) were obtained by using a 2%Au1-Pd1/TiO2 catalyst at 110 °C.

Keywords

• bimetallic nanoparticles
• gold catalysts
• catalysis
• oxidation
• selectivity modulation