Corrosion behavior of AA2024/pure copper bimetal manufactured by friction stir welding with a hybrid zinc-graphite interlayer

Abstract

The effect of utilization of zinc (Zn) and graphite (Gr) as a hybrid interlayer for dissimilar lap joint of AA2024 and pure copper, employing friction stir welding (FSW), was investigated in this study. The microstructure of the samples was examined using a scanning electron microscope (SEM), and the composition of the present phases was evaluated with energy-dispersive spectroscopy (EDS) and X-ray diffraction (XRD). Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests were performed to analyze the corrosion behavior. Subsequently, the post-corrosion morphology was examined using SEM and EDS. The results show that applying two passes of FSW in the presence of hybrid Zn-Gr interlayer, led to the modification of detrimental brittle intermetallic compounds (IMCs). The corrosion investigations demonstrated that the corrosion current density (icorr) in the AA2024/(Zn-Gr)/Cu sample after 1- pass FSW was reduced by about 80% in comparison to the Al/Zn/Cu sample. This behavior can be attributed to the presence of a large number of diffusion channels and the inhibitory effect of graphite particles. The 2-pass FSWed AA2024/(Zn-Gr)/Cu sample exhibited the highest level of corrosion resistance, owing to the better dispersion of graphite particles, which led to improved passivation on the aluminum side. As a result, the inherent issue of intergranular corrosion in the Al–Cu alloy was effectively resolved at the joint interface. This ultimately led to an enhanced corrosion resistance of the Al–Cu bimetals produced by FSW.

Keywords

• AA2024
• Copper
• FSW
• Hybrid interlayer
• Corrosion behavior
• Intermetallic compounds