Ligand‐Promoted [Pd]‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach

Dr. Seetharaman Manojveer; Nitish K. Garg; Zarif Gul; Ayesha Kanwal; Dr. Yogesh Goriya; Dr. Magnus T. Johnson

doi:10.1002/open.202200245

ChemistryOpen (Jan 2023)

Ligand‐Promoted [Pd]‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach

Dr. Seetharaman Manojveer,
Nitish K. Garg,
Zarif Gul,
Ayesha Kanwal,
Dr. Yogesh Goriya,
Dr. Magnus T. Johnson

Affiliations

Dr. Seetharaman Manojveer: Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Nitish K. Garg: Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Zarif Gul: Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Ayesha Kanwal: Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Dr. Yogesh Goriya: Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Dr. Magnus T. Johnson: Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden

DOI: https://doi.org/10.1002/open.202200245
Journal volume & issue: Vol. 12, no. 1
pp. n/a – n/a

Abstract

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Abstract A new class of palladium complexes bearing bidentate 2‐hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal‐ligand cooperative borrowing‐hydrogen (BH) process were demonstrated.

Published in ChemistryOpen

ISSN: 2191-1363 (Online)
Publisher: Wiley-VCH
Country of publisher: Germany
LCC subjects: Science: Chemistry
Website: https://chemistry-europe.onlinelibrary.wiley.com/journal/21911363

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