PeerJ (Aug 2020)
Improving the physical, mechanical and energetic properties of Quercus spp. wood pellets by adding pine sawdust
Abstract
Background Biomass usage for energy purposes has emerged in response to global energy demands and environmental problems. The large amounts of by-products generated during logging are rarely utilized. In addition, some species (e.g., Quercus spp.) are considered less valuable and are left in the cutting areas. Production of pellets from this alternative source of biomass may be possible for power generation. Although the pellets may be of lower quality than other types of wood pellets, because of their physical and technological properties, the addition of different raw materials may improve the characteristics of the oak pellets. Methods Sawdust from the oak species Quercus sideroxyla, Q. rugosa, Q. laeta and Q. conzattii was mixed with sawdust from the pine Pinus durangensis in different ratios of oak to pine (100:0, 80:20, 60:40, 40:60 and 20:80). Physical and mechanical properties of the pellets were determined, and calorific value tests were carried out. For each variable, Kolmogorov–Smirnov normality and Kruskal–Wallis tests were performed and Pearson’s correlation coefficients were determined (considering a significance level of p < 0.05). Results The moisture content and fixed carbon content differed significantly (p < 0.05) between the groups of pellets (i.e., pellets made with different sawdust mixtures). The moisture content of all pellets was less than 10%. However, volatile matter and ash content did not differ significantly between groups (p ≥ 0.05). The ash content was less than 0.7% in all mixtures. The addition of P. durangensis sawdust to the mixtures improved the bulk density of the pellets by 18%. Significant differences (p < 0.05) in particle density were observed between species, mixtures and for the species × mixture interaction. The particle density was highest in the 80:20 and 60:40 mixtures, with values ranging from 1,245 to 1,349 kg m−3. Bulk density and particle density of the pellets were positively correlated with the amount of P. durangensis sawdust included. The mechanical hardness and impact resistance index (IRI) differed significantly (p < 0.05) between groups. The addition of pine sawdust decreased the mechanical hardness of the pellets, up to 24%. The IRI was highest (138) in the Q. sideroxyla pellets (100:0). The mechanical hardness and IRI of the pellets were negatively correlated with the amount of P. durangensis sawdust added. The bulk density of the pellets was negatively correlated with mechanical hardness and IRI. The calorific value of mixtures and the species × mixture interaction differed significantly between groups. Finally, the mean calorific value was highest (19.8 MJ kg−1) in the 20:80 mixture. The calorific value was positively related to the addition of P. durangensis sawdust.
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