Acta Crystallographica Section E (Aug 2011)

Bis(acetonitrile-κN)diaquabis(perchlorato-κO)copper(II)

  • Viktor A. Tafeenko,
  • Stanislav I. Gurskiy,
  • Leonid A. Aslanov

DOI
https://doi.org/10.1107/S1600536811027309
Journal volume & issue
Vol. 67, no. 8
pp. m1125 – m1126

Abstract

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In the title compound, [Cu(ClO4)2(CH3CN)2(H2O)2], the Cu2+ ion, located on a special position (site symmetry overline{1}), is coordinated by six monodentate ligands, viz. an N-coordinated acetonitrile, a perchlorate anion and a water molecule, and their symmetry-related counterparts. The perchlorate anion is disordered over two sets of sites with occupancies of 0.53 (2) and 0.47 (2). The crystal structure is stabilized by O—H...O hydrogen bonds involving the perchlorate ion and aqua H atoms.