Acta Crystallographica Section E (Jan 2009)

Aquabis(6-bromopicolinato-κ2N,O)copper(II)

  • Fei-Long Hu,
  • Zhuang Yue,
  • Mi Yan,
  • Wei-Qiang Luo,
  • Xian-Hong Yin

DOI
https://doi.org/10.1107/S1600536808041536
Journal volume & issue
Vol. 65, no. 1
pp. m45 – m46

Abstract

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In the title compound, [Cu(C6H3BrNO2)2(H2O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water molecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring planes is 67.6 (2)°. In the crystal, O—H...O hydrogen bonds result in chains propagating in [100].