Acta Crystallographica Section E (Mar 2012)

(Z)-4-(2-Hydroxybenzylidene)-1-methyl-2-phenyl-1H-imidazol-5(4H)-one

  • Kew-Yu Chen,
  • Ming-Hui Luo,
  • Hsing-Yang Tsai,
  • Tzu-Chien Fang,
  • Ming-Jen Chang

DOI
https://doi.org/10.1107/S1600536812007921
Journal volume & issue
Vol. 68, no. 3
pp. o902 – o903

Abstract

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In the title compound, C17H14N2O2, the asymmetric unit comprises two molecules that are comformationally similar [the dihedral angles between the phenyl rings in each are 46.35 (2) and 48.04 (3)°], with the conformation stabilized by intramolecular O—H...N hydrogen bonds, which generate S(7) rings. In the crystal, inversion-related molecules are linked by pairs of weak C—H...O hydrogen bonds, forming dimers with an R22(16) graph-set motif. Weak inter-ring π–π stacking is observed in the structure, the shortest centroid-to-centroid distance being 3.7480 (13) Å.