The Effect of Sulphate Anions on the Ultrafine Titania Nucleation

Volodymyr O. Kotsyubynsky; Ivan F. Myronyuk; Volodymyr L. Chelyadyn; Andriy B. Hrubiak; Volodymyr V. Moklyak; Sofia V. Fedorchenko

doi:10.1186/s11671-017-2144-3

Nanoscale Research Letters (May 2017)

The Effect of Sulphate Anions on the Ultrafine Titania Nucleation

Volodymyr O. Kotsyubynsky,
Ivan F. Myronyuk,
Volodymyr L. Chelyadyn,
Andriy B. Hrubiak,
Volodymyr V. Moklyak,
Sofia V. Fedorchenko

Affiliations

Volodymyr O. Kotsyubynsky: Vasyl Stefanyk Precarpathian National University
Ivan F. Myronyuk: Vasyl Stefanyk Precarpathian National University
Volodymyr L. Chelyadyn: Institute of Materials Science I.M. Frantsevich
Andriy B. Hrubiak: Institute of Metal Physics, National Academy of Science
Volodymyr V. Moklyak: Institute of Metal Physics, National Academy of Science
Sofia V. Fedorchenko: Vasyl Stefanyk Precarpathian National University

DOI: https://doi.org/10.1186/s11671-017-2144-3
Journal volume & issue: Vol. 12, no. 1
pp. 1 – 5

Abstract

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Abstract The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)h(OH2)6−h](4−h)+ mononers is the determinative factor for anatase phase nucleation.

Published in Nanoscale Research Letters

ISSN: 1931-7573 (Print); 1556-276X (Online)
Publisher: SpringerOpen
Country of publisher: United Kingdom
LCC subjects: Technology: Electrical engineering. Electronics. Nuclear engineering: Materials of engineering and construction. Mechanics of materials
Website: https://www.springer.com/journal/11671

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