Synthesis of bisnitroepoxides and their applications in the synthesis of bis(thiazolidine-2-thiones), bis(dithiocarbamates), bis(xanthates) and bis(thiazoles)

Abstract

Abstract Novel bis(nitroepoxides) were prepared based on terephthaldehyde and isophthaladehyde and their reactions with diversities of nucleophiles such as primary and secondary amine-based dithiocarbamic acids, xanthates, and ammonia-based dithiocarbmamates were investigated for the synthesis of bis(thiazolidine-2-thiones), bis(dithiocarbamates), bis(xanthates) and bis(thiazoles), respectively. It provides simple access to complex molecules in one step in high to excellent yields.

Keywords

• Nitroepoxides
• Bis(thiazolidine-2-thiones)
• Bis(dithiocarbamates)
• Bis(xanthates)
• Bis(thiazoles)