Acta Crystallographica Section E (Jul 2011)

(Z)-4-(2-Naphthylamino)pent-3-en-2-one

  • Mohamed Anoir Harrad,
  • Brahim Boualy,
  • Abdelghani Oudahmane,
  • Daniel Avignant,
  • Corrado Rizzoli

DOI
https://doi.org/10.1107/S1600536811024494
Journal volume & issue
Vol. 67, no. 7
pp. o1818 – o1818

Abstract

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The title compound, C15H15NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthylamine, adopts a Z conformation about the C=C bond. The enamine–ketone fragment is approximately planar [maximum deviation = 0.026 (3) Å] and forms a dihedral angle of 39.78 (3)° with the naphthalene ring system. An intramolecular N—H...O hydrogen bond is observed.