Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry (Dec 2012)

(-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS

  • S. Kovalskaya,
  • N. Kozlov,
  • A. Aricu,
  • V. Kulcitki,
  • N. Ungur

Journal volume & issue
Vol. 7, no. 2
pp. 147 – 148

Abstract

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The main products of sclareol (1) Ritter’s reaction in mild conditions are (8R,13R)-Labd-14(15)-en-8,13-diacetamide (2) (8R,13S)-Labd-14(15)-en-8,13-diacetamide (3) stereoisomeric on C13 atom and having unrearranged native diol skeleton. We present in the current communication the results of sclareol converting (1) into nitrogen-containing labdanes in the Ritter’s reaction conditions.

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