Remarkable phosphate removal from saline solution by using a novel trimetallic oxide nanocomposite

Abstract

Phosphate removal is an important measure to control eutrophication in aquatic environments, as it inhibits algal bloom. Salinity exists in these media along with high phosphate and currently available phosphate removal methods function poorly under this condition. In this study, the main objective is to fabricate a nanocomposite to improve and accelerate phosphate removal from saline solutions. To achieve this goal, Fe3O4/ZnO and a novel nanoadsorbent, Fe3O4/ZnO/CuO, were synthesized. Their characteristics were determined using FE-SEM, EDX, FT-IR, and XRD analyses, and their capability to adsorb phosphate from saline solutions was investigated and compared. The overall results suggest that the trimetallic oxide nanocomposite has great potential for the efficient removal of phosphate, in comparison with Fe3O4/ZnO. Experiments showed that Fe3O4/ZnO/CuO exhibited a remarkable sorption capacity of 156.35 mg P/g, fast sorption kinetic, strong selectivity for phosphate even in the presence of a high concentration of salinity (60 mg/L), and a wide applicable pH range of 3–6. Furthermore, using Fe3O4/ZnO/CuO, even a low dosage of 0.1 g/L was sufficient to reach an adsorption efficiency of 96.13% within 15 min compared to Fe3O4/ZnO (80.47% within 30 min). Moreover, the pseudo-second-order kinetic model best described the experimental adsorption data for both nanocomposites. HIGHLIGHTS High adsorption capacity of the trimetallic oxide nanocomposite.; Wide applicable pH range of 3–6 of Fe3O4/ZnO/CuO nanocomposite.; Enhanced removal from saline solution by Fe3O4/ZnO/CuO.; More than 45% adsorption rate increase in saline solution by modifying Fe3O4/ZnO.; The pseudo-second-order kinetic model perfectly described removal.;

Keywords

• adsorption
• eutrophication
• fe3o4/zno
• salinity
• trimetallic