Carbonaceous Fe_xP Synthesized via Carbothermic Reduction of Dephosphorization Slag as Hydrogen Evolution Catalyst for Water Splitting

Abstract

Developing the high-efficiency and cheap non-noble catalysts towards hydrogen evolution reaction (HER) is of significance for water splitting. Herein, for the first time, we report a simple method of acid leaching combined with carbothermic reduction with dephosphorization slag to construct a carbonaceous FexP/C catalyst. In alkaline medium, the corresponding overpotential when the output current density was 10 mA cm−2 (η10) was only 145 mV. Additionally, there was no obvious attenuation after 3000 cycles, which showed significantly better activity and stability than that of non-carbonaceous FexP catalysts prepared by gas–solid phosphating. The structure and composition of FexP/C were characterized by X-ray diffraction, scanning electron microscope, energy dispersive spectroscopy, and inductively coupled plasma atomic emission spectrometer. The electrochemical properties of the electrode were evaluated by cyclic voltammetry, linear scanning voltammetry, electrochemical impedance spectroscopy, and cyclic stability. The results showed that the prepared FexP/C was composed of FeP-Fe2P mixed nanocrystals supported on amorphous carbon. Compared with FexP, the synergistic catalysis of the FeP and Fe2P phases as well as the interactive support effect between the FeP-Fe2P mixed nanocrystals and the amorphous carbon support will attribute the rich active sites for electrocatalytic reaction and reduce the charge transfer resistance. Thus, FexP/C has good hydrogen evolution activity and stability. Overall, the preparation of catalysts with high additional value based on dephosphorization slag was preliminarily explored.

Keywords

• water splitting
• hydrogen evolution reaction
• transition metal phosphides
• iron phosphide