Acta Crystallographica Section E (Jul 2011)

3-(2-Bromobenzyl)-1-methyl-1H-imidazol-3-ium bromide

  • Jian-Yu Dong,
  • Tian-Pa You

DOI
https://doi.org/10.1107/S1600536811019842
Journal volume & issue
Vol. 67, no. 7
pp. o1568 – o1568

Abstract

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In the title compound, C11H12BrN2+·Br−, the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71 (7)°. The crystal structure is stabilized by non-classical intermolecular C—H...Br hydrogen bonds and inversion-related molecules are linked through π–π interactions between the imidazole ring systems [centroid–centroid distance = 3.472 (6) Å].