2-(4-Methylsulfanylphenyl)-1H-benzimidazol-3-ium bromide

Abstract

In the cation of the title compound, C14H13N2S+·Br−, the essentially planar benzimidazole system (r.m.s. deviation = 0.0082 Å) is substituted with a 4-methylsulfanylphenyl ring. The dihedral angle between the benzimidazole system and the 4-methylsulfanylphenyl ring is 2.133 (2)°. The crystal structure is characterized by strong and highly directional intermolecular N—H...Br hydrogen bonds involving the bromide ion. Moreover, C—H...S interactions result in chains of molecules along the c axis. The supramolecular assembly is further stabilized by π–π stacking interactions between the benzimidazole system and 4-methylsulfanylphenyl rings [centroid–centroid distance = 3.477 (4) Å].