Acta Crystallographica Section E (Jun 2012)

1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene

  • Dong-mei Ren

DOI
https://doi.org/10.1107/S1600536812023057
Journal volume & issue
Vol. 68, no. 6
pp. o1929 – o1929

Abstract

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In the title compound, C10H9Cl2NO3, the dihedral angle between the benzene ring and the plane of the nitro group is 39.1 (1)°, while that between the benzene ring and the plane through the three C and two Cl atoms of the dichloroallyloxy unit is 40.1 (1)°. In the crystal, C—H...O hydrogen bonds to the nitro groups form chains along the b axis. These chains are linked by inversion-related pairs of Cl...O interactions at a distance of 3.060 (3) Å, forming sheets approximately parallel to [-201] and generating R22(18) rings. π–π contacts between benzene rings in adjacent sheets, with centroid–centroid distances of 3.671 (2) Å, stack molecules along c.