Acta Crystallographica Section E (Sep 2011)

(E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide

  • Shang Shan,
  • Yan-Lan Huang,
  • Han-Qi Guo,
  • Deng-Feng Li,
  • Jian Sun

DOI
https://doi.org/10.1107/S1600536811033101
Journal volume & issue
Vol. 67, no. 9
pp. o2498 – o2498

Abstract

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The title compound, C13H12N2OS, was obtained from the condensation reaction of 2-acetylthiophene and benzohydrazide. In the molecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (13)°, respectively, to the phenyl and thiophene rings. The thiophene and phenyl rings make a dihedral angle of 53.21 (8)°. The benzamide fragment and thiophene ring are located on the opposite sides of the C=N bond, showing an E conformation. Classical intermolecular N—H...O hydrogen bonds and weak C—H...O interactions are present in the crystal structure: three such bonds occur to the same O-atom acceptor.