Physics Open (Dec 2023)
Synthesis of Sr-doped Ni0.5Zn0.5SrxFe2-xO4 and the study of its structural, mechanical, magnetic, and electrical properties for high-frequency applications
Abstract
The solid-state reaction method has been used to mold the spinel Ni–Zn ferrites with doped strontium (Sr) [Ni0.5Zn0.5SrxFe2-xO4; x = 0.00, 0.01, 0.03, 0.05, and 0.10]. The powder X-ray diffraction approach was driven to investigate the crystal lattice of the studied samples. By using a variety of methods, including the Debye-Scherrer (D-S) formula, the Williamson-Hall (W–H), the Halder-Wagner (H–W), and the size-strain plot (SSP), where broadening of the XRD peaks are used, we have calculated the crystallographic features of Ni–Zn ferrites to ascertain the crystallite size and lattice strain. With doped Sr contents in samples, the lattice constants of the studied ferrites were decreased. Scanning electron microscopy (SEM) was used to analyze the sample's surface. Using the Image J software, the samples' grain size was calculated. We also performed the FTIR calculation, which confirmed that the ferrites we studied were spinel ferrites. The stiffness constants and elastic moduli were enumerated using the FTIR data to evaluate the mechanical behavior of the studied samples. Important thermal parameters such as Debye temperature (ΘD) and melting temperature (Tm) were also calculated. The magnetic behavior characterizing parameters have been analyzed via a vibrating sample magnetometer (VSM). Our studied samples are soft magnetic materials. We found the magnetic and electric losses to be negligible. Over a wide frequency extent, from 102 to 106 Hz at ambient temperature, an impedance analyzer was utilized to examine the samples' dielectric properties and AC resistivity. In the high-frequency region, the dielectric constant is frequency independent and the values of the dielectric constant are decreased with doped materials. Resistivity is increased with Sr-doped materials.
