Nature Communications (Nov 2020)

Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature

  • Fang-Fang Tan,
  • Xiao-Ya He,
  • Wan-Fa Tian,
  • Yang Li

DOI
https://doi.org/10.1038/s41467-020-19944-x
Journal volume & issue
Vol. 11, no. 1
pp. 1 – 11

Abstract

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The high bond energies of C–O bonds in biomass and its derivatives make their cleavage very challenging. Here, the authors report a photoredox-catalyzed C–O bond cleavage in diaryl ethers by acidolysis with an aryl carboxylic acid followed by hydrolysis in a one-pot manner.