Leaching Efficiency and Kinetics of Platinum from Spent Proton Exchange Membrane Fuel Cells by H₂O₂/HCl

Abstract

The increasing carbon emissions from various fossil fuels have led to the search for efficient and clean energy sources to replace them. Proton exchange membrane fuel cells (PEMFCs) are a promising alternative, but the use of platinum as a catalyst material poses challenges due to its limited resources and low abundance. This study proposes an efficient method for platinum recovery while retaining spent membranes. The membrane and catalyst were separated using isopropanol, and the spent membrane was dissolved in a 50% ethanol solution to prepare the precursor for subsequent membrane regeneration. Hydrochloric acid (HCl) was used as the leaching agent, and the experimental parameters such as HCl concentration, H2O2 concentration, contact time, and operating temperature were optimized to achieve the highest platinum leaching rate. Finally, through isothermal leaching experiments, the leaching mechanism was investigated using the shrinking core model, indicating the involvement of both surface chemical and inner diffusion mechanisms in the platinum leaching process, primarily controlled by the inner diffusion mechanism. Under optimal conditions, the platinum leaching rate was about 90%, and the activation energy of the reaction was calculated to be 6.89 kJ/mol using the Arrhenius equation.

Keywords

• PEMFC
• platinum
• leaching
• leaching kinetics
• shrinking core model