Nature Communications (Jan 2017)

Edge reactivity and water-assisted dissociation on cobalt oxide nanoislands

  • J. Fester,
  • M. García-Melchor,
  • A. S. Walton,
  • M. Bajdich,
  • Z. Li,
  • L. Lammich,
  • A. Vojvodic,
  • J. V. Lauritsen

DOI
https://doi.org/10.1038/ncomms14169
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 8

Abstract

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Earth abundant transition metal oxides show great promise as catalysts for the oxygen evolution reaction. Here, the authors reveal a self-assisted water dissociation mechanism and favourable theoretical adsorption energetics for water oxidation at the edge sites of cobalt oxide nano-islands.