Water adsorption on acetylene black carbon

Abstract

Differential heat, isotherm, thermokinetics, and entropy of water adsorption on the black carbon were studied by the adsorption-calorimetric method at 303 K. The adsorption mechanism, type, and number of formed ion-molecular complexes were determined. Thermokinetics of adsorption on the black carbon and the law of migration of exchange cations were determined, and the adsorption energy of gases and vapors was calculated. The adsorption isotherm is described by the two-and three-dimensional mathematical equations of the volume-saturation theory of micro-pores (TVSM).