Selective hydrosilylation of allyl chloride with trichlorosilane

Koya Inomata; Yuki Naganawa; Zhi An Wang; Kei Sakamoto; Kazuhiro Matsumoto; Kazuhiko Sato; Yumiko Nakajima

doi:10.1038/s42004-021-00502-5

Communications Chemistry (May 2021)

Selective hydrosilylation of allyl chloride with trichlorosilane

Koya Inomata,
Yuki Naganawa,
Zhi An Wang,
Kei Sakamoto,
Kazuhiro Matsumoto,
Kazuhiko Sato,
Yumiko Nakajima

Affiliations

Koya Inomata: Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)
Yuki Naganawa: Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)
Zhi An Wang: Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)
Kei Sakamoto: Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)
Kazuhiro Matsumoto: Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)
Kazuhiko Sato: Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)
Yumiko Nakajima: Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)

DOI: https://doi.org/10.1038/s42004-021-00502-5
Journal volume & issue: Vol. 4, no. 1
pp. 1 – 9

Abstract

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Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.

Published in Communications Chemistry

ISSN: 2399-3669 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry
Website: https://www.nature.com/commschem

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