Comparative Performance Evaluation of Magnetron Sputtered TiN, AlCrN, and TiAlCrN Coatings

Abstract

This study presents a comparative performance evaluation of magnetron-sputtered TiN, AlCrN, and TiAlCrN coatings on tool steel substrates. Coatings play a pivotal role in enhancing the durability of engineering components exposed to harsh conditions. TiN is known for outstanding hardness and durability, AlCrN for superior wear resistance, and TiAlCrN for exceptional thermal stability and oxidation resistance. The substrate (EN 1.2363) underwent PVD coating using a closed-field unbalanced magnetron sputter ion plating (CFUBMSIP) process in a water-cooled stainless-steel vacuum chamber with four magnetron ports, operating for 3 hours per batch followed by 12 hours of natural convection cooling, utilizing TiN, AlCrN, and TiAlCrN films deposited for 180 minutes in an Ar and nitrogen atmosphere. X-ray diffraction (XRD) revealed distinctive crystal structures, with all coatings exhibiting a common preferred orientation of the (111) plane and TiAlCrN showing a ternary nitride phase. Scanning electron microscopy (SEM) images displayed the compact nature of TiAlCrN with finer grains, while TiN exhibited a densely compacted with no evidence of delamination and AlCrN showed denseness with smaller grains. Nano-indentation test was conducted to assess the coatings' hardness and elastic modulus. TiAlCrN exhibited the highest hardness (3091±243 HV), highest elastic modulus (369.86±54.19 GPa), and the best wear rate (0.1887 x 10-4 mm3/Nm-1) suggesting potential suitability for applications demanding superior rigidity and wear resistance. The study provides valuable insights for materials scientists and engineers in optimizing coating selection for specific applications.

Keywords

• Magnetron Sputtering
• TiAlCrN
• Thin film deposition
• Nanoindentation
• Hardness