Facile Hydrothermal Synthesis of Cu₂MoS₄ and FeMoS₄ for Efficient Adsorption of Chlortetracycline

Abstract

Contamination of antibiotics in an aqueous environment has attracted wide attention. Developing high-efficiency adsorbents for antibiotics removal is urgent. In this work, two kinds of ternary transition metal chalcogenides—Cu2MoS4 and FeMoS4 with superior adsorption performance were prepared by a facile hydrothermal synthesis method. The microstructure and physicochemical properties of the adsorbents were analyzed by X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The as-prepared Cu2MoS4 and FeMoS4 were found to have dramatic potential for the adsorption of chlortetracycline (CTC) in an aqueous solution with an extremely high adsorption capacity. The Langmuir maximum adsorption capacity of Cu2MoS4 and FeMoS4 to CTC can reach 1203.81 and 2169.19 mg/g, respectively, which goes far beyond the common adsorbents as reported. Moreover, the adsorption kinetics, thermodynamics as well as adsorption mechanism were examined in detail by a batch of adsorption experiments.

Keywords

• transition metal chalcogenides
• adsorption
• antibiotics
• Cu₂MoS₄
• FeMoS₄
• water treatment