Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)]

Abstract

In the binuclear title complex, [Er2(C13H9N3O2)2Cl2(CH3OH)2], the entire molecule is generated by the application of inversion symmetry. Each ErIII ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzylidene)pyridine-2-carbohydrazidate (L2−) ligand, one O atom and one N atom from the symmetry-related L2− ligand, one O atom of a methanol molecule and one chloride anion. The coordination geometry is based on a pseudo-pentagonal bipyramid. Linear supramolecular chains along [010] are formed in the crystal packing through O—H...Cl hydrogen bonds.