Communications Materials (Jun 2024)

Crack mitigation in additively manufactured AlCrFe2Ni2 high-entropy alloys through engineering phase transformation pathway

  • Shahryar Mooraj,
  • Xizhen Dong,
  • Shengbiao Zhang,
  • Yanming Zhang,
  • Jie Ren,
  • Shuai Guan,
  • Chenyang Li,
  • Rameshwari Naorem,
  • Nicolas Argibay,
  • Wei Chen,
  • Wentao Yan,
  • Dierk Raabe,
  • Zhongji Sun,
  • Wen Chen

DOI
https://doi.org/10.1038/s43246-024-00542-z
Journal volume & issue
Vol. 5, no. 1
pp. 1 – 13

Abstract

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Abstract The far-from-equilibrium solidification during additive manufacturing often creates large residual stresses that induce solid-state cracking. Here we present a strategy to suppress solid-state cracking in an additively manufactured AlCrFe2Ni2 high-entropy alloy via engineering phase transformation pathway. We investigate the solidification microstructures formed during laser powder-bed fusion and directed energy deposition, encompassing a broad range of cooling rates. At high cooling rates (104−106 K/s), we observe a single-phase BCC/B2 microstructure that is susceptible to solid-state cracking. At low cooling rates (102−104 K/s), FCC phase precipitates out from the BCC/B2 matrix, resulting in enhanced ductility (~10 %) and resistance to solid-state cracking. Site-specific residual stress/strain analysis reveals that the ductile FCC phase can largely accommodate residual stresses, a feature which helps relieve residual strains within the BCC/B2 phase to prevent cracking. Our work underscores the value of exploiting the toolbox of phase transformation pathway engineering for material design during additive manufacturing.