Beilstein Journal of Organic Chemistry (Dec 2014)
A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
Abstract
An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.
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