Study on the thermal oxidation stability of an endothermic hydrocarbon fuel(吸热型碳氢燃料的热氧化安定性研究)

YUJin-hua(余金花); LIDan(李丹); GUOYong-sheng(郭永胜); FANGWen-jun(方文军); LINRui-sen(林瑞森)

doi:zjup/1008-9497.2007.34.2.185-188

Zhejiang Daxue xuebao. Lixue ban (Mar 2007)

Study on the thermal oxidation stability of an endothermic hydrocarbon fuel(吸热型碳氢燃料的热氧化安定性研究)

YUJin-hua(余金花),
LIDan(李丹),
GUOYong-sheng(郭永胜),
FANGWen-jun(方文军),
LINRui-sen(林瑞森)

Affiliations

YUJin-hua(余金花): Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江　杭州　310027)
LIDan(李丹): Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江　杭州　310027)
GUOYong-sheng(郭永胜): Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江　杭州　310027)
FANGWen-jun(方文军): Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江　杭州　310027)
LINRui-sen(林瑞森): Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江　杭州　310027)

DOI
Journal volume & issue: Vol. 34, no. 2
pp. 185 – 188

Abstract

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采用静态法测定了自行研制的吸热型碳氢燃料ZH-100在加强氧化条件下的热氧化安定性能，用红外光谱检测ZH-100热氧化前后官能团的变化.结果表明，在160 ℃下加强氧化5 h后燃料组分中除了原有的—CH3和—CH2—官能团外，还明显检出了羟基、羰基和碳碳双键3种官能团，红外分析结果很好地解释了燃料经加强氧化后颜色发生变化的原因.通过碘量比色法对氧化过程中生成的过氧化物进行定量分析，解释了燃料的热氧化反应机理，评价了3种抗氧化剂的效果.结果显示合适的抗氧化剂可以使燃料的热氧化安定性有一定程度的提高.

Published in Zhejiang Daxue xuebao. Lixue ban

ISSN: 1008-9497 (Print)
Publisher: Zhejiang University Press
Country of publisher: China
LCC subjects: Science: Mathematics: Instruments and machines: Electronic computers. Computer science; Science: Physics
Website: https://www.zjujournals.com/sci/EN/1008-9497/home.shtml

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