Nanoporosity and Isosteric Enthalpy of Adsorption of CH₄, H₂, and CO₂ on Natural Chabazite and Exchanged

Abstract

This paper describes the isosteric enthalpy through narrow pores at low levels of coverage through adsorption of CO2, CH4, and H2 on pores in natural chabazite exchanged with aqueous solutions of Na+, Mg2+, and Ca2+ salts at different concentrations, and with variable time and temperature of treatment. Experimental data of CO2, CH4, and H2 adsorption were treated by the Freundlich and Langmuir equations. Complementarily, the degree of interaction of these gases with these zeolites was evaluated by the evolution of isosteric enthalpy of adsorption. The exchange with Mg2+ and Na+ favors an increase in the adsorption capacity for CO2. while that of Ca2+ and Mg2+ favor adsorption through to H2 and CH4. These cations occupy sites in strategic positions S4 and S4’, which are located in the channels and nanocavities of these zeolites. The presence of Ca2+ and Mg2+ at S4 and S4′ sites causes increased adsorption into the nanocavities and on the external area of the ion-exchanged zeolites. Depending on the conditions of the exchange treatment, Ca2+ and Mg2+, and Na+ were found to be most favorable, well distributed, and accessible for CO2, CH4, and H2 adsorption.

Keywords

• CO₂
• CH₄
• H₂
• chabazite
• adsorption
• nanopores