Thermo-driven oleogel-based self-healing slippery surface behaving superior corrosion inhibition to Mg-Li alloy

Yibo Ouyang; Huijun Kang; Enyu Guo; Ri Qiu; Keqiang Su; Zongning Chen; Tongmin Wang

Journal of Magnesium and Alloys (Dec 2023)

Thermo-driven oleogel-based self-healing slippery surface behaving superior corrosion inhibition to Mg-Li alloy

Yibo Ouyang,
Huijun Kang,
Enyu Guo,
Ri Qiu,
Keqiang Su,
Zongning Chen,
Tongmin Wang

Affiliations

Yibo Ouyang: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China
Huijun Kang: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China; Ningbo Institute of Dalian University of Technology, Ningbo 315000, PR China
Enyu Guo: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China; Ningbo Institute of Dalian University of Technology, Ningbo 315000, PR China; Corresponding authors at: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China.
Ri Qiu: College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, PR China; State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266101, PR China; Institute of Yellow River Delta Earth Surface Processes and Ecological Integrity, Shandong University of Science and Technology, PR China; Corresponding author at: College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, PR China.
Keqiang Su: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China
Zongning Chen: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China; Ningbo Institute of Dalian University of Technology, Ningbo 315000, PR China
Tongmin Wang: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China; Ningbo Institute of Dalian University of Technology, Ningbo 315000, PR China; Corresponding authors at: Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China.

Journal volume & issue: Vol. 11, no. 12
pp. 4710 – 4723

Abstract

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Bioinspired by Nepenthes, lubricant infused surfaces (LIS) have attracted widespread attention in the field of anticorrosion. However, the lubricant coating has some disadvantages such as complex construction processing and easy loss of oil phase in air or dynamic water phase. In this study, oleogel is infused into a lotus leaf inspired super-hydrophobic matrix to form an oleogel infused surface (OIS) for enhancing corrosion resistance of active Mg-Li alloy. For reserving oleogel, firstly, a facile one-step electrodeposition method is used to construct super-hydrophobic surface (SHS) composed by samarium/myristic acid complex micro-nano flower structure onto Mg-Li alloy. The coating exhibits excellent superhydrophobic property at a static contact angle of 160° by applying 30 V electrolysis for 30 min. The protection efficiency of single SHS highly relates with the metal itself. For short period immersion in water phase, SHS can afford protection to Mg-Li alloy. However, the long-term immersion will see the rapid failure of SHS, and the high activity of Mg-Li alloy is one main reason. We assume that SHS cannot be a good choice for protecting Mg-Li alloy. Then, a Nepenthes inspired liquid coating is formed by infusing oleogel into the micro-nano structure by a spin-coating method. The liquid coating performs prominent corrosion resistance with Rct reaching as high as 1.51 × 1010 Ω cm². After the mechanical damage from the external environment, the liquid coating can realize self-repair through thermal assistance, and the liquid coating can still restore Rct up to 1.24 × 1010 Ω cm2 after healing. The corrosion resistance of the liquid coating remains strong by showing Rct as high as 1.14 × 109 Ω cm², even after immersion in representative corrosive 3.5 wt% NaCl solution for 30 d.

Published in Journal of Magnesium and Alloys

ISSN: 2213-9567 (Online)
Publisher: KeAi Communications Co., Ltd.
Country of publisher: China
LCC subjects: Technology: Mining engineering. Metallurgy
Website: https://www.keaipublishing.com/en/journals/journal-of-magnesium-and-alloys/

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