Acta Crystallographica Section E (Jan 2013)

μ-Azido-κ2N1:N1-μ-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)] chloroform monosolvate

  • Ana C. Mafud,
  • Milene A. R. Oliviera,
  • Maria T. P. Gambardella

DOI
https://doi.org/10.1107/S1600536812047927
Journal volume & issue
Vol. 69, no. 1
pp. m15 – m15

Abstract

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In the binuclear title complex, [Pd2(C11H13ClN)2Cl(N3)]·CHCl3, each PdII atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethylamino-1-phenylpropyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intramolecular C—H...Cl contact in the complex molecule. In the crystal, the chloroform solvent molecule is linked to the complex via a C—H...π interaction.