Acta Crystallographica Section E (Jan 2013)
μ-Azido-κ2N1:N1-μ-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)] chloroform monosolvate
Abstract
In the binuclear title complex, [Pd2(C11H13ClN)2Cl(N3)]·CHCl3, each PdII atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethylamino-1-phenylpropyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intramolecular C—H...Cl contact in the complex molecule. In the crystal, the chloroform solvent molecule is linked to the complex via a C—H...π interaction.