BioResources (Feb 2016)

Lignin-based Foams: Production Process and Characterization

  • Gianluca Tondi,
  • Martin Link,
  • Christian Kolbitsch,
  • Johannes Gavino,
  • Paul Luckeneder,
  • Alexander Petutschnigg,
  • Richard Herchl,
  • Charlie Van Doorslaer

DOI
https://doi.org/10.15376/biores.11.2.2972-2986
Journal volume & issue
Vol. 11, no. 2
pp. 2972 – 2986

Abstract

Read online

Lignin foams are innovative materials obtained by the copolymerization of furanics with the spent liquor from the magnefite wood pulping process. In this study, the influence of the component amount in the formulation, as well as the effect of temperature on the final product, were elucidated. Several formulations, with various lignin/furanic ratios, blowing agents, and catalyst concentrations, exhibited good homogeneity and densities between 185 and 407 kg m-3. The mechanical properties, as well as the thermal conductivities, confirmed the strong dependence on density, and the results obtained were comparable to that of tannin foams. The leaching tests revealed that the lignin foams released a certain amount of catalyst within the first minutes of water dipping. However the pH of this leachate stabilized quickly, which suggests that the catalyst can be easily recovered.

Keywords