Nature Communications (Sep 2016)

Tuning graphitic oxide for initiator- and metal-free aerobic epoxidation of linear alkenes

  • Samuel Pattisson,
  • Ewa Nowicka,
  • Upendra N. Gupta,
  • Greg Shaw,
  • Robert L. Jenkins,
  • David J. Morgan,
  • David W. Knight,
  • Graham J. Hutchings

DOI
https://doi.org/10.1038/ncomms12855
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 9

Abstract

Read online

Graphitic oxide is readily produced by the oxidation of graphite. Here the authors show that the amount and nature of the oxidant can be used to tune the properties of graphitic oxide, and furthermore report a carbocatalyst for alkene epoxidation without the need for metal or initiators.