Scientific Reports (Mar 2023)

Silver-assisted reduction of nitroarenes by an Ag-embedded curcumin/melamine-functionalized magnetic nanocatalyst

  • Nima Khaleghi,
  • Mohadeseh Forouzandeh-Malati,
  • Fatemeh Ganjali,
  • Zahra Rashvandi,
  • Simindokht Zarei-Shokat,
  • Reza Taheri-Ledari,
  • Ali Maleki

DOI
https://doi.org/10.1038/s41598-023-32560-1
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 17

Abstract

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Abstract In the current study, we introduce a hybrid magnetic nanocomposite comprised of curcumin (Cur), iron oxide magnetic nanoparticles (Fe3O4 MNPs), melamine linker (Mel), and silver nanoparticles (Ag NPs). Initially, a facile in situ route is administrated for preparing the Fe3O4@Cur/Mel-Ag effectual magnetic catalytic system. In addition, the advanced catalytic performance of the nanocomposite to reduce the nitrobenzene (NB) derivatives as hazardous chemical substances were assessed. Nevertheless, a high reaction yield of 98% has been achieved in short reaction times 10 min. Moreover, the Fe3O4@Cur/Mel-Ag magnetic nanocomposite was conveniently collected by an external magnet and recycled 5 times without a noticeable diminish in catalytic performance. Therefore, the prepared magnetic nanocomposite is a privileged substance for NB derivatives reduction since it achieved notable catalytic activity.