MgAl-NO₃ LDH: Adsorption Isotherms and Multivariate Optimization for Cr(VI) Removal

Abstract

Within the framework of the various strategies studied for the abatement of polluting agents in water, both from anthropogenic and natural origins, adsorption processes are among the most widespread techniques. In this context, Layered Double Hydroxides (LDHs) play a fundamental role. In this study, a Mg–Al LDH (nitrate intercalated, Mg/Al = 2) was prepared to be used as an anion exchanger for Cr(VI)-removal purposes from water. The LDH was synthesized through a coprecipitation reaction, followed by an aging process under heating. The compound was characterized by means of inductively coupled plasma–atomic emission spectroscopy (ICP-AES), X-ray powder diffraction (XRPD), field-emission scanning electron microscopy (FE-SEM) and Fourier-transform infrared spectroscopy (FT-IR). Regarding LDH adsorption capacity, with respect to Cr(VI), the adsorption isotherms and reaction kinetic were studied, and the adsorption process was well described by the Langmuir model. A central composite design was used for the multivariate optimization of the working parameters. The maximum adsorption capacity was estimated to be 30 mg/g.

Keywords

• MgAl-NO₃ LDH
• chromium (VI) removal
• adsorption isotherm
• experimental design