Quantum Dots-Sensitized High Electron Mobility Transistor (HEMT) for Sensitive NO₂ Detection

Abstract

Colloidal quantum dots (CQDs) are gaining increasing attention for gas sensing applications due to their large surface area and abundant active sites. However, traditional resistor-type gas sensors using CQDs to realize molecule recognition and signal transduction at the same time are associated with the trade-off between sensitivity and conductivity. This limitation has restricted their range of practical applications. In this study, we propose and demonstrate a monolithically integrated field-effect transistor (FET) gas sensor. This novel FET-type gas sensor utilizes the capacitance coupling effect of the CQD sensing film based on a floating gate, and the quantum capacitance plays a role in the capacitance response of the CQD sensing film. By effectively separating the gate sensing film from the two-dimensional electron gas (2DEG) conduction channel, the lead sulfide (PbS) CQD gate-sensitized FET gas sensor offers high sensitivity, a high signal-to-noise ratio, and a wide range, with a real-time response of sub-ppb NO2. This work highlights the potential of quantum dot-sensitized FET gas sensors as a practical solution for integrated gas sensor chip applications using CQDs.

Keywords

• colloidal quantum dot
• PbS
• FET-type gas sensor
• ligand exchange
• capacitance