Acta Crystallographica Section E (Sep 2009)

4-{(Z)-(sec-Butylamino)(phenyl)methylene}-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one

  • Hai-Zhen Xu,
  • Jian-Ping Xu,
  • Yan-Wei Yuan,
  • Jin Zhang,
  • You-Quan Zhu

DOI
https://doi.org/10.1107/S160053680902950X
Journal volume & issue
Vol. 65, no. 9
pp. o2116 – o2116

Abstract

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In the title compound, C21H23N3O, the dihedral angles formed by the pyrazolone ring with two phenyl rings are 10.38 (8) and 76.94 (6)°. The sec-butylamino group is disordered over two positions, with refined site-occupancy factors of 0.730 (4) and 0.270 (4). The compound could potentially be ligand stabilized in the solid state in a keto–enamine tautomeric form. The amine functionality is involved in an intramolecular N—H...O hydrogen bond, while weak intermolecular C—H...O and C—H...N hydrogen bonds participate in the formation of the crystal structure.