Acta Crystallographica Section E (Oct 2011)

(4-Bromo-2-{[2-(morpholin-4-yl)ethylimino]methyl}phenolato)dioxidovanadium(V)

  • Cai-Jun Yuan,
  • Feng Cao,
  • Xiang Wu,
  • Chen-Yi Wang

DOI
https://doi.org/10.1107/S1600536811035240
Journal volume & issue
Vol. 67, no. 10
pp. m1330 – m1330

Abstract

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In the title mononuclear dioxidovanadium(V) complex, [V(C13H16BrN2O2)O2], the VV atom is five-coordinated by one phenolate O, one imine N and one morpholine N atom of the Schiff base ligand, and by two oxide O atoms, forming a distorted square-pyramidal geometry. In the crystal, weak C—H...O interactions and a short Br...Br contact [3.4597 (12) Å] are observed.