Nature Communications (Feb 2017)

Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid

  • Jin Lin,
  • Zhi Li,
  • Jian Kan,
  • Shijun Huang,
  • Weiping Su,
  • Yadong Li

DOI
https://doi.org/10.1038/ncomms14353
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 7

Abstract

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C–H bond functionalization has become an important tool for many organic transformations, however such reactions typically require stoichiometric amounts of external oxidants. Here the authors report the photo-driven decarboxylative C–H trifluoromethylation of arenes using only low amounts of oxidant.