Characterization of Monodispersed γ-Al2O3 Particles, Synthesized by Homogeneous Precipitation under Reflux Boiling

Abstract

In this study, micron size uniform particles of aluminum compounds were synthesized by the homogeneous precipitation method under reflux boiling, using aluminum nitrate, urea and potassium sulfate as starting materials. In this method, varying amounts of the reactants were heated in a Pyrex glass round bottom flask at the boiling temperature for various periods of time, which led to the production of precipitated particles in the reactant mixtures. Scanning electron microscopic (SEM) examination of the precipitated particles revealed that uniformity in particle morphology of the precipitated particles was dependent on the applied experimental conditions. As such, the latter were extensively optimized for obtaining particles of uniform morphology and size. Some of the batches of the precipitated particles were calcined at the elevated temperature (800 and 1000 °C) for transformation into crystalline solids. Similarly, the as prepared and calcined particles were characterized by SEM, XRD, TGA/DTA and FTIR. XRD results revealed that at 1000 °C of calcinations, the as prepared amorphous alumina transformed in to crystalline state, while below this temperature, i.e. at 800 °C calcination, the powder was amorphous in nature. The point of zero charge (PZC) of the desired sample was estimated by the salt addition method.

Keywords

• homogenous precipitation
• reflux boiling
• monodispersed γ-al2o3 particles
• point of zero charge
• 65.80.-g