Acta Crystallographica Section E (Dec 2011)

1,3-Bis(propan-2-yl)naphthalene

  • Bernd Schröder,
  • Ligia Rebelo Gomes,
  • John Nicolson Low

DOI
https://doi.org/10.1107/S1600536811047854
Journal volume & issue
Vol. 67, no. 12
pp. o3334 – o3334

Abstract

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In the title compound, C16H20, one of the isopropyl groups shows almost equal displacements [1.252 (1) and −1.270 (1) Å] of its methyl-C atoms from the mean plane of the naphthalene ring system, while the other shows asymmetric displacements [1.586 (2) and −0.315 (1) Å]. In the crystal, the molecules are linked into sheets lying in the ab plane by three C—H...π contacts, two involving donors belonging to the isopropyl groups and the third a donor atom from the naphthalene ring system. The different orientations of the isopropyl groups might be attributed to the fact that the C—H...π interaction involving one of them is enhanced by the C—H...π interaction involving the aromatic ring.