Magnetically Induced Near-Infrared Circularly Polarized Electroluminescence from an Achiral Perovskite Light-Emitting Diode

Abstract

Circularly polarized electroluminescent devices are conventionally fabricated by incorporating an optically active chiral luminophore into their emission layer. Herein, we developed a circularly polarized perovskite light-emitting diode (PeLED) system with an optically inactive perovskite luminophore that can emit near-infrared circularly polarized electroluminescence (CPEL) upon application of an external magnetic field. The magnitude of the magnetic CPEL (gMCPEL) was in the order of 10−3 in the near-infrared wavelength range of 771–773 nm. Although the Pb perovskite quantum dots were achiral, the rotation direction of the CPEL of the magnetic circularly polarized PeLED system was successfully reversed by switching the Faraday geometry of the applied magnetic field. The use of achiral luminophores exhibiting magnetic-field-induced CPEL represents a new approach for the development of circularly polarized electroluminescent devices.

Keywords

• chiral
• circularly polarized luminescence
• circularly polarized perovskite light-emitting diode
• circularly polarized organic light-emitting diode
• near-infrared circularly polarized electroluminescence
• perovskite quantum dot