Combined NO_x and NH₃ Slip Reduction in a Stoker Boiler Equipped with the Hybrid SNCR + SCR System FJBS+

Abstract

The application of secondary NOx control methods in medium to low-capacity furnaces is a relatively new topic on the energy market and thus requires further research. In this paper, the results of full-scale research of SNCR and hybrid SNCR + SCR methods applied into a 29 MWth solid fuel fired stoker boiler is presented. The tests were performed for a full range of boiler loads, from 33% (12 MWth) to 103% (30 MWth) of nominal load. A novel SNCR + SCR hybrid process was demonstrated based on an enhanced in-furnace SNCR installation coupled with TiO2-WO3-V2O5 catalyst, which provides extra NOx reduction and works as an excess NH3 “catcher” as well. The performance of a brand-new catalyst was evaluated in comparison to a recovered one. The emission of NOx was reduced below 180 mg NOx/Nm3 at 6% O2, with ammonia slip in flue gas below 10 mg/Nm3. Special attention was paid to the analysis of ammonia slip in combustion products: flue gas and fly ash. An innovative and cost-effective method of ammonia removal from fly ash was presented and tested. The main idea of this method is fly ash recirculation onto the grate. As a result, ammonia content in fly ash was reduced to a level below 6.1 mg/kg.

Keywords

• selective non-catalytic reduction
• selective catalytic reduction
• NH₃ slip
• catalyst regeneration
• stoker boiler
• fly ash