Acta Crystallographica Section E (Jun 2012)

3-{[Bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5-methylbenzaldehyde

  • Ruo-Xu Wang,
  • Da-Zhi Gao,
  • Fan Ye,
  • Yan-Fei Wu,
  • Dun-Ru Zhu

DOI
https://doi.org/10.1107/S1600536812019940
Journal volume & issue
Vol. 68, no. 6
pp. o1672 – o1673

Abstract

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In the title compound, C21H21N3O2, the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The molecular conformation is stabilized by intramolecular bifurcated O—H...N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C—H...N hydrogen bonds.