The Dilemma of C-Rate and Cycle Life for Lithium-Ion Batteries under Low Temperature Fast Charging

Abstract

Electric vehicles (EVs) in severe cold regions face the real demand for fast charging under low temperatures, but low-temperature environments with high C-rate fast charging can lead to severe lithium plating of the anode material, resulting in rapid degradation of the lithium-ion battery (LIB). In this paper, by constructing an electrode–thermal model coupling solid electrolyte interphase (SEI) growth and lithium plating, the competition among different factors of capacity degradation under various ambient temperatures and C-rates are systematically analyzed. In addition, the most important cause of rapid degradation of LIBs under low temperatures are investigated, which reveal the change pattern of lithium plating with temperature and C-rate. The threshold value and kinetic law of lithium plating are determined, and a method of lithium-free control under high C-rate is proposed. Finally, by studying the average aging rate of LIBs, the reasons for the abnormal attenuation of cycle life at lower C-rates are ascertained. Through the chromaticity diagram of the expected life of LIBs under various conditions, the optimal fast strategy is explored, and its practical application in EVs is also discussed. This study can provide a useful reference for the development of high-performance and high-safety battery management systems to achieve fine management.

Keywords

• lithium-ion battery (LIB)
• fast charging
• solid electrolyte interface (SEI)
• lithium plating
• low temperature