Effective removal of cation dyes from aqueous solution using robust cellulose sponge

Abstract

Cellulose sponge was proposed to an attractive bio-absorbent owing to its highly efficient, low-cost, biodegradable, and renewable sourcing. In this work, the wasted cotton linter as raw materials, the highly porous and lightweight cellulose sponges were synthesized via a facile chemical crosslinking and freeze-drying process. The resultant cellulose sponge (CA) exhibited an interconnected three-dimensional porous structure through crosslinked with N,N′-methylene bisacrylamide (MBA), which was beneficial to remove organic dyestuffs. The effects of various factors including solution pH, contact time, initial dye concentration, and ionic strength on the adsorption behavior were investigated in detail. Herein, Langmuir isotherm models were selected to determine the adsorption capacity, and the maximum theoretical adsorption capacity for Methylene blue (MB) and Crystal violet (CV) was 123.46 and 76.63 mg/g, respectively. Particularly, the results of kinetic and thermodynamic tests showed that the adsorption performance was a spontaneous endothermic reaction and the adsorption process followed the pseudo-second-order kinetic. Furthermore, cellulose sponges could maintain maximum adsorption capacity even after twelve cycles. Therefore, the eco-friendly cellulose sponge would be a promising adsorbent for effective wastewater treatment.

Keywords

• Cellulose sponge
• Chemical crosslinking
• Absorption kinetics