Chemical Pressure

Abstract

The physical and photophysical properties of three classic transition metal complexes, namely [Fe(bpy)3]2+, [Ru(bpy)3]2+, and [Co(bpy)3]2+, can be tuned by doping them into a variety of inert crystalline host lattices. The underlying guest-host interactions are discussed in terms of a chemical pressure.

Keywords

• Chemical pressure
• [co(bpy)3]2
• [fe(bpy)3]2
• Guest-host interaction
• Intersystem crossing
• Luminescence