Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

Satoshi Takebayashi; Tsubasa Shizuno; Takashi Otani; Takanori Shibata

doi:10.3762/bjoc.8.212

Beilstein Journal of Organic Chemistry (Oct 2012)

Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

Satoshi Takebayashi,
Tsubasa Shizuno,
Takashi Otani,
Takanori Shibata

Affiliations

Satoshi Takebayashi: Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Okubo, Shinjuku, Tokyo, 169-8555, Japan
Tsubasa Shizuno: Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Okubo, Shinjuku, Tokyo, 169-8555, Japan
Takashi Otani: Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Okubo, Shinjuku, Tokyo, 169-8555, Japan
Takanori Shibata: Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Okubo, Shinjuku, Tokyo, 169-8555, Japan

DOI: https://doi.org/10.3762/bjoc.8.212
Journal volume & issue: Vol. 8, no. 1
pp. 1844 – 1848

Abstract

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[RhCp*(OAc)2(H2O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4·OEt2. A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.

Published in Beilstein Journal of Organic Chemistry

ISSN: 1860-5397 (Online)
Publisher: Beilstein-Institut
Country of publisher: Germany
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.beilstein-journals.org/bjoc

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